1
This is him coat.
This is his coat.
His can be a possessive adjective, also called a possessive determiner. We use it before a noun: ‘This is his coat.’
2
This coat is him.
This coat is his.
His can also be a possessive pronoun. In this case, we use it without a noun: ‘This coat is his.’
Unlike her/hers, the form his is the same before a noun and when it is used alone.
See MINE