I arrived to Barcelona at midday.
I arrived in Barcelona at midday.
I arrived to the station too late.
I arrived at the station too late.
We use arrive in with cities, countries and large areas, for example arrive in London, arrive in England and arrive in Yorkshire.
We use arrive at with specific places and events, for example arrive at the station, arrive at the airport and arrive at a party.
Do not use arrive to before a place. We use no preposition before home, here or there: ‘We arrived home late.’